KMS Shanghai Institute of Ceramics，Chinese Academy of Sciences
| Electron-pinned defect dipoles in (Li, Al) co-doped ZnO ceramics with colossal dielectric permittivity | |
| Huang, D; Li, WL; Liu, ZF; Li, YX; Ton-That, C; Cheng, JQ; Choy, WCH; Ling, FCC | |
| 2020-03-07 | |
| Source Publication | JOURNAL OF MATERIALS CHEMISTRY A
 |
| ISSN | 2050-7488 |
| Issue | 9Pages:4764 |
| Subtype | Article |
| Abstract | Through systematic optimization studies of Li and Al co-doped ZnO ceramics we demonstrate that colossal permittivity with low dielectric loss (epsilon(r) = 9862 and tan d = 0.159 at the frequency of 1 kHz) at room temperature can be achieved in Zn-0.99(Li-0.1, Al-0.2)(0.033)O. The colossal dielectric constant (CDC) and low dielectric loss in this ceramic have relatively good frequency and temperature stability. Annealing the ceramic at 900 degrees C in oxygen leads to the drop of 3r to 2250 but the dielectric loss remains at similar to 0.10. Dielectric spectrum analysis shows that the CDC is associated with two relaxation processes. One of these process vanishes and the other one persists after annealing, suggesting that P1 is associated with oxygen-deficient defects. For samples exhibiting CDC, ac conductivity study revealed correlated barrier hopping between defect states in the band gap. A model involving these defects as the electron pinned defect dipole is proposed. The experimental dielectric data are well described by this model using Kirkwood's theory and Kramer-Kronig transformation. |
| DOI | 10.1039/c9ta12808e |
| WOS Keyword | FERROELECTRICITY ; RELAXATION ; TIO2 ; CACU3TI4O12 ; BEHAVIOR |
| Language | 英语 |
| WOS Research Area | Chemistry ; Energy & Fuels ; Materials Science |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sic.ac.cn/handle/331005/28236 |
| Collection | 中国科学院上海硅酸盐研究所 |
| Recommended Citation GB/T 7714 | Huang, D,Li, WL,Liu, ZF,et al. Electron-pinned defect dipoles in (Li, Al) co-doped ZnO ceramics with colossal dielectric permittivity[J]. JOURNAL OF MATERIALS CHEMISTRY A,2020(9):4764. |
| APA | Huang, D.,Li, WL.,Liu, ZF.,Li, YX.,Ton-That, C.,...&Ling, FCC.(2020).Electron-pinned defect dipoles in (Li, Al) co-doped ZnO ceramics with colossal dielectric permittivity.JOURNAL OF MATERIALS CHEMISTRY A(9),4764. |
| MLA | Huang, D,et al."Electron-pinned defect dipoles in (Li, Al) co-doped ZnO ceramics with colossal dielectric permittivity".JOURNAL OF MATERIALS CHEMISTRY A .9(2020):4764. |
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