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Mossbauer Study of the Effect of Cation Substitutions on the Magnetic Phase Transitions in BiFe1-xCrxO3 and (1-x)BiFeO3-xPbFe(0.5)Sb(0.5)O(3) Solid Solutions
Kubrin, SP; Raevski, IP; Olekhnovich, NM; Pushkarev, AV; Radyush, YV; Titov, VV; Malitskaya, MA; Li, GR; Raevskaya, SI
2020-05-01
Source PublicationCRYSTALLOGRAPHY REPORTS
ISSN1063-7745
Issue3Pages:338
SubtypeArticle; Proceedings Paper
AbstractThe concentration dependences of the magnetic phase transition temperature T-N, determined based on the changes in Mossbauer spectra, were investigated for a BiFeO3 solid solution with ordered perovskite PbFe0.5Sb0.5O3 and for a disordered BiFe1 - xCrxO3 solid solution. It is established that the magnetic-order type in BiFe1 - xCrxO3 changes from antiferromagnetic to spin-glass at a higher degree of Fe-sublattice dilution in comparison with the PbFe0.5Nb0.5O3-based solid solutions presumably because of the smaller BiFeO3 lattice parameter. Due to the local ordering of Fe3+ and Sb5+ ions, the T-N value decreases more rapidly (as compared to BiFe1 - xCrxO3) with a decrease in the Fe3+ content in the lattice of (1 - x)BiFeO3- xPbFe(0.5)Sb(0.5)O(3) solid solutions.
DOI10.1134/S1063774520030165
WOS KeywordCERAMICS ; PBFE0.5NB0.5O3 ; MULTIFERROICS ; IONS
Language英语
WOS Research AreaCrystallography
PublisherPLEIADES PUBLISHING INC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/28089
Collection中国科学院上海硅酸盐研究所
Recommended Citation
GB/T 7714
Kubrin, SP,Raevski, IP,Olekhnovich, NM,et al. Mossbauer Study of the Effect of Cation Substitutions on the Magnetic Phase Transitions in BiFe1-xCrxO3 and (1-x)BiFeO3-xPbFe(0.5)Sb(0.5)O(3) Solid Solutions[J]. CRYSTALLOGRAPHY REPORTS,2020(3):338.
APA Kubrin, SP.,Raevski, IP.,Olekhnovich, NM.,Pushkarev, AV.,Radyush, YV.,...&Raevskaya, SI.(2020).Mossbauer Study of the Effect of Cation Substitutions on the Magnetic Phase Transitions in BiFe1-xCrxO3 and (1-x)BiFeO3-xPbFe(0.5)Sb(0.5)O(3) Solid Solutions.CRYSTALLOGRAPHY REPORTS(3),338.
MLA Kubrin, SP,et al."Mossbauer Study of the Effect of Cation Substitutions on the Magnetic Phase Transitions in BiFe1-xCrxO3 and (1-x)BiFeO3-xPbFe(0.5)Sb(0.5)O(3) Solid Solutions".CRYSTALLOGRAPHY REPORTS .3(2020):338.
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