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Nanoheterostructures of Partially Oxidized RuNi Alloy as Bifunctional Electrocatalysts for Overall Water Splitting
Lin, GX; Wang, YD; Hong, J; Suenaga, K; Liu, LJ; Chang, LY; Pao, CW; Zhang, T; Zhao, W; Huang, FQ; Yang, MH; Sun, YY; Wang, JC
2020-05-22
Source PublicationCHEMSUSCHEM
ISSN1864-5631
Issue10Pages:2739
SubtypeArticle
AbstractElectrocatalytic water splitting, as one of the most promising methods to store renewable energy generated by intermittent sources, such as solar and wind energy, has attracted tremendous attention in recent years. Developing efficient, robust, and green catalysts for the hydrogen and oxygen evolution reactions (HER and OER) is of great interest. This study concerns a facile and green approach for producing RuNi/RuNi oxide nanoheterostructures by controllable partial oxidation of RuNi nanoalloy, which is characterized and confirmed by various techniques, including high-resolution transmission electron microscopy and synchrotron-based X-ray absorption spectroscopy. This nanoheterostructure demonstrates outstanding bifunctional activities for catalyzing the HER and OER with overpotentials that are both among the lowest reported values. In a practical alkali-water-splitting electrolyzer, it also achieves a record-low cell voltage of 1.42 V at 10 mA cm(-2), which is significantly superior to the commercial RuO2//Pt/C couple and other reported bifunctional water-splitting electrocatalysts. Density functional theory calculations are employed to elaborate the effect of Ni incorporation. This simple catalyst preparation approach is expected to be transferrable to other electrocatalytic reactions.
DOI10.1002/cssc.202000213
WOS KeywordOXYGEN EVOLUTION ; HIGHLY EFFICIENT ; HYDROGEN ; DESIGN
Language英语
WOS Research AreaChemistry ; Science & Technology - Other Topics
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/28043
Collection中国科学院上海硅酸盐研究所
Recommended Citation
GB/T 7714
Lin, GX,Wang, YD,Hong, J,et al. Nanoheterostructures of Partially Oxidized RuNi Alloy as Bifunctional Electrocatalysts for Overall Water Splitting[J]. CHEMSUSCHEM,2020(10):2739.
APA Lin, GX.,Wang, YD.,Hong, J.,Suenaga, K.,Liu, LJ.,...&Wang, JC.(2020).Nanoheterostructures of Partially Oxidized RuNi Alloy as Bifunctional Electrocatalysts for Overall Water Splitting.CHEMSUSCHEM(10),2739.
MLA Lin, GX,et al."Nanoheterostructures of Partially Oxidized RuNi Alloy as Bifunctional Electrocatalysts for Overall Water Splitting".CHEMSUSCHEM .10(2020):2739.
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