KMS Shanghai Institute of Ceramics,Chinese Academy of Sciences
Structural, dielectric, ferroelectric, and magnetic properties of lead-free (1-x)BiFe0.95Ga0.03Mn0.02O3 - xBaTiO(3) ceramics | |
Yan, MY; Yan, JM; Wang, H; Wu, Y; Wang, FF; Zheng, RK | |
2020-06-01 | |
Source Publication | CERAMICS INTERNATIONAL
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ISSN | 0272-8842 |
Issue | 8Pages:12705 |
Subtype | Article |
Abstract | We report the structural, dielectric, ferroelectric and magnetic properties of (1-x) BiFe0.95Ga0.03Mn0.02O3 - xBaTiO(3) (BFGMO -xBTO) lead-free ceramics. Structural characterizations demonstrate that the BFGMO forms single-phase solid solutions with the BTO within the doping level of x = 0.3-0.65. With increasing the content of BTO the dielectric constant and ferroelectric Curie temperature shift towards lower temperatures, exhibiting relaxor-like ferroelectric behaviors. Moreover, the remnant polarization reaches the maximum value of 2P(r) similar to 27.67 mu C/cm(2) at x = 0.35 near the morphotropic phase boundary. At room temperature, remnant magnetization increases - to the maximal value of 2M(r) similar to 0.584 emu/g at x = 0.45, which is attributed to local lattice distortion and destruction of the spiral antiferromagnetic spin structure upon the doping of BTO. The coexistence of ferroelectric and ferromagnetic performance at room temperature makes the environment-friendly BFGMO - xBTO ceramics potential candidate for multiferroic device applications. |
DOI | 10.1016/j.ceramint.2020.02.037 |
WOS Keyword | PHASE-TRANSITIONS ; PERFORMANCE |
Language | 英语 |
WOS Research Area | Materials Science |
Publisher | ELSEVIER SCI LTD |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sic.ac.cn/handle/331005/28029 |
Collection | 中国科学院上海硅酸盐研究所 |
Recommended Citation GB/T 7714 | Yan, MY,Yan, JM,Wang, H,et al. Structural, dielectric, ferroelectric, and magnetic properties of lead-free (1-x)BiFe0.95Ga0.03Mn0.02O3 - xBaTiO(3) ceramics[J]. CERAMICS INTERNATIONAL,2020(8):12705. |
APA | Yan, MY,Yan, JM,Wang, H,Wu, Y,Wang, FF,&Zheng, RK.(2020).Structural, dielectric, ferroelectric, and magnetic properties of lead-free (1-x)BiFe0.95Ga0.03Mn0.02O3 - xBaTiO(3) ceramics.CERAMICS INTERNATIONAL(8),12705. |
MLA | Yan, MY,et al."Structural, dielectric, ferroelectric, and magnetic properties of lead-free (1-x)BiFe0.95Ga0.03Mn0.02O3 - xBaTiO(3) ceramics".CERAMICS INTERNATIONAL .8(2020):12705. |
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