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Water-Stable High Lithium-Ion Conducting Solid Electrolyte of Li-1.Al-4(0).Ge-4(0).Ti-2(1).(4)(PO4)(3)-LiCl for Aqueous Lithium-Air Batteries
Bai, F; Kakimoto, K; Shang, XF; Mori, D; Taminato, S; Matsumoto, M; Takeda, Y; Yamamoto, O; Izumi, H; Minami, H; Imanishi, N
2020-08-07
Source PublicationFRONTIERS IN ENERGY RESEARCH
ISSN2296-598X
SubtypeArticle
AbstractAqueous lithium-air batteries are one of the most promising batteries for electric vehicles because of its high energy and power density. The battery system consists of a lithium anode and an aqueous solution catholyte, which are separated by a water-stable lithium-ion-conducting solid electrolyte, and an air electrode. The theoretical energy density of this system is 1,910 W h kg(-1), which is around five times higher than that of conventional lithium-ion batteries. A key component of this system is the water-stable lithium-ion-conducting solid electrolyte. In this work, we have developed a water-stable and water-impermeable solid electrolyte with a high lithium-ion conductivity of around 10(-3)S cm(-1)at room temperature by the addition of epoxy resin and LiCl into a tape-cast NASICON-type Li-1.Al-4(0).Ge-4(0).Ti-2(1).(4)(PO4)(3)film. The aqueous lithium-air battery with the solid electrolyte separator was successfully cycled at 0.5 mA cm(-2)and 25 degrees C in an air atmosphere.
DOI10.3389/fenrg.2020.00187
WOS KeywordCATHODE ; LISICON ; METAL ; ANODE
Language英语
WOS Research AreaEnergy & Fuels
PublisherFRONTIERS MEDIA SA
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Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/27844
Collection中国科学院上海硅酸盐研究所
Recommended Citation
GB/T 7714
Bai, F,Kakimoto, K,Shang, XF,et al. Water-Stable High Lithium-Ion Conducting Solid Electrolyte of Li-1.Al-4(0).Ge-4(0).Ti-2(1).(4)(PO4)(3)-LiCl for Aqueous Lithium-Air Batteries[J]. FRONTIERS IN ENERGY RESEARCH,2020.
APA Bai, F.,Kakimoto, K.,Shang, XF.,Mori, D.,Taminato, S.,...&Imanishi, N.(2020).Water-Stable High Lithium-Ion Conducting Solid Electrolyte of Li-1.Al-4(0).Ge-4(0).Ti-2(1).(4)(PO4)(3)-LiCl for Aqueous Lithium-Air Batteries.FRONTIERS IN ENERGY RESEARCH.
MLA Bai, F,et al."Water-Stable High Lithium-Ion Conducting Solid Electrolyte of Li-1.Al-4(0).Ge-4(0).Ti-2(1).(4)(PO4)(3)-LiCl for Aqueous Lithium-Air Batteries".FRONTIERS IN ENERGY RESEARCH (2020).
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