KMS Shanghai Institute of Ceramics，Chinese Academy of Sciences
| From nanomelting to nanobeads: nanostructured SbxBi1-x alloys anchored in three-dimensional carbon frameworks as a high-performance anode for potassium-ion batteries | |
| He, Xiao-Dong; Liao, Jia-Ying; Wang, Shuo; Wang, Jun-Ru; Liu, Ze-Hua; Ding, Xiang; Hu, Qiao; Wen, Zhao-Yin; Chen, Chun-Hua | |
| 2019-12-21 | |
| Source Publication | JOURNAL OF MATERIALS CHEMISTRY A
 |
| ISSN | 2050-7488 |
| Volume | 7Issue:47Pages:27041 |
| Subtype | Article |
| Abstract | Potassium-ion batteries (KIBs) are considered a favorable candidate for large-scale electric energy storage system applications owing to the abundance and low-cost of potassium resources. Herein, a series of three-dimensional pomegranate-like SbxBi1-x@C composites are fabricated by a modified Pechini sol-gel method. As an anode for KIBs, the Sb0.5Bi0.5@C composite exhibits the optimal performance (382 mA h g(-1) at 0.05 A g(-1)). More importantly, the synergistic effects in the binary alloy bring a promising long-term cycle life (83% capacity retention after 400 cycles) for Sb0.5Bi0.5@C. The ex situ X-ray diffraction results reveal the K storage mechanism of this material, which is Sb0.5Bi0.5 <-> KSb0.5Bi0.5 <-> K3Sb0.5Bi0.5 during discharge and charge processes. In addition, a full cell constructed by coupling Sb0.5Bi0.5@C with a Prussian blue cathode delivers outstanding electrochemical performance. |
| DOI | 10.1039/c9ta10755j |
| WOS Keyword | LONG CYCLE LIFE ; INTERCALATION ; NANOCOMPOSITE ; COMPOSITE |
| Language | 英语 |
| WOS Research Area | Chemistry ; Energy & Fuels ; Materials Science |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sic.ac.cn/handle/331005/27442 |
| Collection | 中国科学院上海硅酸盐研究所 |
| Recommended Citation GB/T 7714 | He, Xiao-Dong,Liao, Jia-Ying,Wang, Shuo,et al. From nanomelting to nanobeads: nanostructured SbxBi1-x alloys anchored in three-dimensional carbon frameworks as a high-performance anode for potassium-ion batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2019,7(47):27041. |
| APA | He, Xiao-Dong.,Liao, Jia-Ying.,Wang, Shuo.,Wang, Jun-Ru.,Liu, Ze-Hua.,...&Chen, Chun-Hua.(2019).From nanomelting to nanobeads: nanostructured SbxBi1-x alloys anchored in three-dimensional carbon frameworks as a high-performance anode for potassium-ion batteries.JOURNAL OF MATERIALS CHEMISTRY A,7(47),27041. |
| MLA | He, Xiao-Dong,et al."From nanomelting to nanobeads: nanostructured SbxBi1-x alloys anchored in three-dimensional carbon frameworks as a high-performance anode for potassium-ion batteries".JOURNAL OF MATERIALS CHEMISTRY A 7.47(2019):27041. |
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