SIC OpenIR
Enhanced Photoelectric SrOCuSbS2 of a [SrO]-Intercalated CuSbS2 Structure
Bu, Kejun; Luo, Mengjia; Wang, Ruiqi; Zhang, Xian; He, Jianqiao; Wang, Dong; Zhao, Wei; Huang, Fuqiang
2019-01-07
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume58Issue:1Pages:69
SubtypeArticle
AbstractA new two-dimensional (2D) layered oxysulfide, namely, SrOCuSbS2, was successfully synthesized at 160 degrees C by using a hydrazine-hydrothermal method. The compound crystallizes in the space group C-2h(2)-P2(1)/m (No. 11) of the monoclinic system. The crystal structure is composed of distorted chalcostibite-like (2)(infinity)[CuSbS2O](2-) layers along the ab plane, in which the adjacent layers are separated by Sr2+ ions. Each layer contains infinite (1)(infinity)[Cu2S6](10-) chains linked by [SbS4O](7-) units. The optical band gap of the compound is 1.9 eV, presenting the dark red color. Due to the electronic insulating layer (EIL) of the SrO, SrOCuSbS2 shows a high photoelectric property with a photocurrent density of 3.S mA/cm(2) at 1 V. The results of density of states (DOS) reveal that the valence band maximum (VBM) mainly consists of Cu-3d and S-3p states, while Sb-5p, S-3p, and S-3s contribute to the conductive band minimum (CBM).
DOI10.1021/acs.inorgchem.8b03082
Language英语
WOS Research AreaChemistry
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/27406
Collection中国科学院上海硅酸盐研究所
Recommended Citation
GB/T 7714
Bu, Kejun,Luo, Mengjia,Wang, Ruiqi,et al. Enhanced Photoelectric SrOCuSbS2 of a [SrO]-Intercalated CuSbS2 Structure[J]. INORGANIC CHEMISTRY,2019,58(1):69.
APA Bu, Kejun.,Luo, Mengjia.,Wang, Ruiqi.,Zhang, Xian.,He, Jianqiao.,...&Huang, Fuqiang.(2019).Enhanced Photoelectric SrOCuSbS2 of a [SrO]-Intercalated CuSbS2 Structure.INORGANIC CHEMISTRY,58(1),69.
MLA Bu, Kejun,et al."Enhanced Photoelectric SrOCuSbS2 of a [SrO]-Intercalated CuSbS2 Structure".INORGANIC CHEMISTRY 58.1(2019):69.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Bu, Kejun]'s Articles
[Luo, Mengjia]'s Articles
[Wang, Ruiqi]'s Articles
Baidu academic
Similar articles in Baidu academic
[Bu, Kejun]'s Articles
[Luo, Mengjia]'s Articles
[Wang, Ruiqi]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Bu, Kejun]'s Articles
[Luo, Mengjia]'s Articles
[Wang, Ruiqi]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.