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Fluoroborophosphates: a family of potential deep ultraviolet NLO materials
Wu, Baolin; Hu, Chunli; Tang, Ruling; Mao, Feifei; Feng, Jianghe; Mao, Jianggao
2019-03-01
Source PublicationINORGANIC CHEMISTRY FRONTIERS
ISSN2052-1553
Volume6Issue:3Pages:723
SubtypeArticle
AbstractA series of new acentric fluoroborophosphates, namely, RbBPO4F, CsBPO4F and (NH4)(2)BPO4F2, have been obtained by combining BO3F or BO2F2 with a PO4 tetrahedron. The structures of the isomeric RbBPO4F and CsBPO4F feature a three-dimensional diamond framework, in which a BO3F (or PO4) tetrahedron corner is shared with three PO4 (or BO3F) tetrahedra, forming 1D tunnels of eight-membered rings (MRs) along the three axial directions, which are filled with alkali cations. (NH4)(2)BPO4F2 exhibits a 3D supramolecular structure, in which 1D [BPO4F2](infinity)(1) anionic chains along the a axes based on corner-sharing and alternating PO4 and BO2F2 tetrahedra are further interconnected with ammonium cations by electrostatic attractions and hydrogen bonds. RbBPO4F, CsBPO4F and (NH4)(2)BPO4F2 display second-harmonic generation (SHG) signals approximately 0.4, 0.6 and 0.8 times that of KH2PO4 (KDP) and exhibit short UV absorption edges (< 200 nm). Measurements of thermal stability and optical properties and theoretical calculations have also been performed.
DOI10.1039/c9qi00006b
Language英语
WOS Research AreaChemistry
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/27298
Collection中国科学院上海硅酸盐研究所
Recommended Citation
GB/T 7714
Wu, Baolin,Hu, Chunli,Tang, Ruling,et al. Fluoroborophosphates: a family of potential deep ultraviolet NLO materials[J]. INORGANIC CHEMISTRY FRONTIERS,2019,6(3):723.
APA Wu, Baolin,Hu, Chunli,Tang, Ruling,Mao, Feifei,Feng, Jianghe,&Mao, Jianggao.(2019).Fluoroborophosphates: a family of potential deep ultraviolet NLO materials.INORGANIC CHEMISTRY FRONTIERS,6(3),723.
MLA Wu, Baolin,et al."Fluoroborophosphates: a family of potential deep ultraviolet NLO materials".INORGANIC CHEMISTRY FRONTIERS 6.3(2019):723.
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