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Oxygen vacancy-assisted hydrogen evolution reaction of the Pt/WO3 electrocatalyst
Tian, Han; Cui, Xiangzhi; Zeng, Liming; Su, Liang; Song, Yiling; Shi, Jianlin
2019-03-21
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
ISSN2050-7488
Volume7Issue:11Pages:6285
SubtypeArticle
AbstractDeveloping novel hydrogen evolution reaction (HER) catalysts with high activity, high stability and low cost is of great importance for the ever-broader applications of hydrogen energy. Among the conventionally used platinum-based heterogeneous catalysts, the high consumption but low utilization efficiency of precious platinum is one of the most crucial issues. Herein we present a facile approach to prepare an effective HER catalyst with platinum atom clusters highly dispersed in WO3@CFC (carbon fiber cloth). The fabricated Pt/def-WO3@CFC electrocatalyst shows an overpotential of 42 mV at 10 mA cm(-2) for the HER in 0.5 M H2SO4, which is highly comparable to that of the state-of-the-art commercial Pt/C catalysts (34 mV), and more attractively, largely enhanced mass activity of Pt and excellent electrochemical stability compared to that of commercial Pt/C. The excellent HER performance of Pt/def-WO3@CFC is attributed to the synergetic catalytic effect between highly dispersed Pt atom clusters and WO3 nanoplates with oxygen vacancies, which enhances both electrocatalytic activity and durability.
DOI10.1039/c8ta12219a
Language英语
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/27263
Collection中国科学院上海硅酸盐研究所
Recommended Citation
GB/T 7714
Tian, Han,Cui, Xiangzhi,Zeng, Liming,et al. Oxygen vacancy-assisted hydrogen evolution reaction of the Pt/WO3 electrocatalyst[J]. JOURNAL OF MATERIALS CHEMISTRY A,2019,7(11):6285.
APA Tian, Han,Cui, Xiangzhi,Zeng, Liming,Su, Liang,Song, Yiling,&Shi, Jianlin.(2019).Oxygen vacancy-assisted hydrogen evolution reaction of the Pt/WO3 electrocatalyst.JOURNAL OF MATERIALS CHEMISTRY A,7(11),6285.
MLA Tian, Han,et al."Oxygen vacancy-assisted hydrogen evolution reaction of the Pt/WO3 electrocatalyst".JOURNAL OF MATERIALS CHEMISTRY A 7.11(2019):6285.
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