KMS Shanghai Institute of Ceramics,Chinese Academy of Sciences
Sintering behavior of high-concentration Li2CO3-doped BaTiO3 ceramics | |
Lou, Q. W.; Zeng, J. T.; Man, Z. Y.; Zheng, L. Y.; Park, C. H.; Li, G. R. | |
2019-04-01 | |
Source Publication | APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
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ISSN | 0947-8396 |
Volume | 125Issue:4 |
Subtype | Article |
Abstract | Li+ ion-doped BaTiO3 (LBT-x, x=0, 3%, 5%, 7%) ceramics were prepared by the solid-state reaction method, which were analyzed by XRD and EDS. The Ba2TiO4 phase was formed on the surface of sintered LBT-x ceramics with high Li+ concentration (x=5%, 7%), and tetragonal phase appeared after the removal of Ba2TiO4 surface layer. According to the results from first-principle calculation of 2x2x2 and 3x3x3 supercells, Li+ ions can occupy B site of ABO(3) perovskite structure. The LBT-x (x=3%, 5%, 7%) ceramics showed antiferroelectric-like double hysteresis loops which form [Li-Ti-V-o](-) dipoles and pin the domain walls. The piezoelectric constant d(33) also decreases due to pinning effect. |
DOI | 10.1007/s00339-019-2556-2 |
Language | 英语 |
WOS Research Area | Materials Science ; Physics |
Publisher | SPRINGER HEIDELBERG |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sic.ac.cn/handle/331005/27224 |
Collection | 中国科学院上海硅酸盐研究所 |
Recommended Citation GB/T 7714 | Lou, Q. W.,Zeng, J. T.,Man, Z. Y.,et al. Sintering behavior of high-concentration Li2CO3-doped BaTiO3 ceramics[J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING,2019,125(4). |
APA | Lou, Q. W.,Zeng, J. T.,Man, Z. Y.,Zheng, L. Y.,Park, C. H.,&Li, G. R..(2019).Sintering behavior of high-concentration Li2CO3-doped BaTiO3 ceramics.APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING,125(4). |
MLA | Lou, Q. W.,et al."Sintering behavior of high-concentration Li2CO3-doped BaTiO3 ceramics".APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING 125.4(2019). |
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