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Transition metal ion-preintercalated V2O5 as high-performance aqueous zinc-ion battery cathode with broad temperature adaptability
Yang, Yongqiang; Tang, Yan; Liang, Shuquan; Wu, Zhuoxi; Fang, Guozhao; Cao, Xinxin; Wang, Chao; Lin, Tianquan; Pan, Anqiang; Zhou, Jiang
2019-07-01
Source PublicationNANO ENERGY
ISSN2211-2855
Volume61Pages:617
SubtypeArticle
AbstractRechargeable aqueous zinc-ion batteries (ZIBs) with advantages of high safety and low-cost gradually show potential in large-scale energy storage/supply application. Yet the further development of aqueous ZIBs is hindered by finding suitable cathodes. Here we demonstrate that the chemical pre-intercalated transition metal ions (e.g. Fe2+, Co2+, Ni2+, Mn2+, Zn2+ and Cu2+, etc.) into the interlayer of V2O5, could effectively improve the electrochemical performance of aqueous ZIBs, in terms of high capacity, rate capability and long-term cycling stability, as well as excellent broad temperature adaptability. For instance, Cu2+-intercalated V2O5 cathode exhibits high capacity of 180 mA h g(-1) after 10000 cycles at 10 A g(-1) and 122 mA h g(-1) after 3000 cycles at 20 A g(-1). This universal strategy of pre-intercalated metal ions in the host materials is found to enable fast Zn2+ diffusion, enhanced electrical conductivity, and excellent structural reversibility, which can be applicable for other well-established aqueous ZIBs cathodes (i.e. MnO2), or other advanced battery systems.
KeywordAqueous zinc-ion battery Vanadium pentoxide Transition metal ion Cycling performance Energy storage mechanism
DOI10.1016/j.nanoen.2019.05.005
Language英语
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
PublisherELSEVIER SCIENCE BV
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Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/27013
Collection中国科学院上海硅酸盐研究所
Recommended Citation
GB/T 7714
Yang, Yongqiang,Tang, Yan,Liang, Shuquan,et al. Transition metal ion-preintercalated V2O5 as high-performance aqueous zinc-ion battery cathode with broad temperature adaptability[J]. NANO ENERGY,2019,61:617.
APA Yang, Yongqiang.,Tang, Yan.,Liang, Shuquan.,Wu, Zhuoxi.,Fang, Guozhao.,...&Zhou, Jiang.(2019).Transition metal ion-preintercalated V2O5 as high-performance aqueous zinc-ion battery cathode with broad temperature adaptability.NANO ENERGY,61,617.
MLA Yang, Yongqiang,et al."Transition metal ion-preintercalated V2O5 as high-performance aqueous zinc-ion battery cathode with broad temperature adaptability".NANO ENERGY 61(2019):617.
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