Defect passivation of CsPbI2Br perovskites through Zn(II) doping: toward efficient and stable solar cells

doi:10.1007/s11426-019-9486-0

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	Defect passivation of CsPbI2Br perovskites through Zn(II) doping: toward efficient and stable solar cells
	Lu, Jiajun; Chen, Shan-Ci; Zheng, Qingdong
	2019-08-01
Source Publication	SCIENCE CHINA-CHEMISTRY
ISSN	1674-7291
Volume	62 Issue:8 Pages:1044
Subtype	Article
Abstract	Defect passivation is an important strategy to achieve perovskite solar cells (PVSCs) with enhanced power conversion efficiencies (PCEs) and improved stability because the trap states induced by defects in the interfaces and grain boundaries of perovskites are harmful to both large open circuit voltage and high photocurrent of devices. Here, zinc cations (Zn2+) were used as a dopant to passivate defects of the CsPbI2Br perovskite leading to Zn2+-doped CsPbI2Br film with fewer trap states, improved charge transportation, and enhanced light-harvesting ability. Thus, the best-performance PVSC based on CsPbI2Br with the optimal Zn2+ doping shows a higher PCE of 12.16% with a larger open-circuit voltage (V-OC) of 1.236 V, an improved shortcircuit current (J(SC)) of 15.61 mA cm(-2) in comparison with the control device based on the pure CsPbI2Br which exhibits a PCE of 10.21% with a V-OC of 1.123 V, a J(SC) of 13.27 mA cm(-2). Time-resolved photoluminescence results show that the Zn2+ doping leads to perovskite film with extended photoluminescence lifetime which means a longer diffusion length and subsequently enhanced photocurrent and open circuit voltage. This work provides a simple strategy to boost the performance of PVSCs through Zn2+ doping.
Keyword	CsPbI2Br perovskites defect passivation Zn(II) doping all-inorganic perovskite solar cells power conversion efficiency
DOI	10.1007/s11426-019-9486-0
Language	英语
WOS Research Area	Chemistry
Publisher	SCIENCE PRESS
Citation statistics
Document Type	期刊论文
Identifier	http://ir.sic.ac.cn/handle/331005/26941
Collection	中国科学院上海硅酸盐研究所
Recommended Citation GB/T 7714	Lu, Jiajun,Chen, Shan-Ci,Zheng, Qingdong. Defect passivation of CsPbI2Br perovskites through Zn(II) doping: toward efficient and stable solar cells[J]. SCIENCE CHINA-CHEMISTRY,2019,62(8):1044.
APA	Lu, Jiajun,Chen, Shan-Ci,&Zheng, Qingdong.(2019).Defect passivation of CsPbI2Br perovskites through Zn(II) doping: toward efficient and stable solar cells.SCIENCE CHINA-CHEMISTRY,62(8),1044.
MLA	Lu, Jiajun,et al."Defect passivation of CsPbI2Br perovskites through Zn(II) doping: toward efficient and stable solar cells".SCIENCE CHINA-CHEMISTRY 62.8(2019):1044.

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