SIC OpenIR
High-Performance RuCl3 Catalyst Systems for Hydro-Esterification of Methyl Formate and Ethylene
Li, Yan-Ru; Xu, Zhong-Ning; Bai, Bing; Wang, Zhi-Qiao; Guo, Guo-Cong
2019-08-01
Source PublicationCHINESE JOURNAL OF CHEMISTRY
ISSN1001-604X
Volume37Issue:8Pages:769
SubtypeArticle
AbstractRuCl3 catalyst system has many advantages for the hydro-esterification of methyl formate and ethylene to methyl propionate. However, the unsatisfied performance restricts the development of this route. In this work, high-performance RuCl3 catalyst systems (RuCl3-[PPN]Cl-Et4NI and RuCl3-NaI) are firstly reported for this reaction. In RuCl3-[PPN]Cl-Et4NI catalyst system, the conversion of methyl formate and the selectivity to methyl propionate are 93.9% and 90.9% at mild reaction conditions (165 degrees C, 2.5 MPa), respectively. Noticeably, a simple inorganic RuCl3-NaI catalyst system achieves 88.8% conversion of methyl formate and 97.6% selectivity to methyl propionate (86.7% yield) at same conditions. NaI, as a promoter, may inhibit the decomposition of methyl formate and be conducive to the formation of methyl propionate. The effects of solvents and promoters are investigated in detail. In addition, the reaction mechanism has been also analyzed. It is hoped to lay a certain foundation for further industrial application.
DOI10.1002/cjoc.201900084
Language英语
WOS Research AreaChemistry
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/26940
Collection中国科学院上海硅酸盐研究所
Recommended Citation
GB/T 7714
Li, Yan-Ru,Xu, Zhong-Ning,Bai, Bing,et al. High-Performance RuCl3 Catalyst Systems for Hydro-Esterification of Methyl Formate and Ethylene[J]. CHINESE JOURNAL OF CHEMISTRY,2019,37(8):769.
APA Li, Yan-Ru,Xu, Zhong-Ning,Bai, Bing,Wang, Zhi-Qiao,&Guo, Guo-Cong.(2019).High-Performance RuCl3 Catalyst Systems for Hydro-Esterification of Methyl Formate and Ethylene.CHINESE JOURNAL OF CHEMISTRY,37(8),769.
MLA Li, Yan-Ru,et al."High-Performance RuCl3 Catalyst Systems for Hydro-Esterification of Methyl Formate and Ethylene".CHINESE JOURNAL OF CHEMISTRY 37.8(2019):769.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Li, Yan-Ru]'s Articles
[Xu, Zhong-Ning]'s Articles
[Bai, Bing]'s Articles
Baidu academic
Similar articles in Baidu academic
[Li, Yan-Ru]'s Articles
[Xu, Zhong-Ning]'s Articles
[Bai, Bing]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Li, Yan-Ru]'s Articles
[Xu, Zhong-Ning]'s Articles
[Bai, Bing]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.