SIC OpenIR
Multiresponsive UV-One-Photon Absorption, Near-Infrared-Two Photon Absorption, and X/gamma-Photoelectric Absorption Luminescence in One [Cu4I4] Compound
Yin, Shao-Yun; Wang, Zheng; Liu, Zhi-Min; Yu, Hui-Juan; Zhang, Jian-Hua; Wang, Yong; Mao, Rihua; Pan, Mei; Su, Cheng-Yong
2019-08-19
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume58Issue:16Pages:10736
SubtypeArticle
AbstractA new Cu4I4-cluster-based compound is constructed to show multifaceted photoluminescent attributes: (1) ultraviolet (UV)-excited thermo-, mechano-, and rigido-chromic phosphorescence by the OPA (one-photon absorption) pathway, due to the interchanging emissions from cluster-centered ((CC)-C-3) and halide-to-ligand charge-transfer ((XLCT)-X-3) excited triplet states, (2) the ability to convert X/gamma-ray and near-infrared (NIR) radiation to visible-light emission, in which the heavy Cu4I4 cores serve as the efficient X/gamma-PEA (photoelectric absorption) or NIR-TPA (two-photon absorption) trapper and convertor to photons in the visible spectrum from the same emissive triplet states as those produced by UV excitation. This all-in-one compound affords a highly integrated nanolab for understanding and exploiting a wide range of photophysical phenomena simultaneously and is further fabricated into fiber-coupled long-range, in situ cryogenic thermometer and poly(methyl methacrylate) (PMMA)-embedded monolith gel, providing access to advanced applications in multifunctional optical materials and devices.
DOI10.1021/acs.inorgchem.9b00876
Language英语
WOS Research AreaChemistry
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/26897
Collection中国科学院上海硅酸盐研究所
Recommended Citation
GB/T 7714
Yin, Shao-Yun,Wang, Zheng,Liu, Zhi-Min,et al. Multiresponsive UV-One-Photon Absorption, Near-Infrared-Two Photon Absorption, and X/gamma-Photoelectric Absorption Luminescence in One [Cu4I4] Compound[J]. INORGANIC CHEMISTRY,2019,58(16):10736.
APA Yin, Shao-Yun.,Wang, Zheng.,Liu, Zhi-Min.,Yu, Hui-Juan.,Zhang, Jian-Hua.,...&Su, Cheng-Yong.(2019).Multiresponsive UV-One-Photon Absorption, Near-Infrared-Two Photon Absorption, and X/gamma-Photoelectric Absorption Luminescence in One [Cu4I4] Compound.INORGANIC CHEMISTRY,58(16),10736.
MLA Yin, Shao-Yun,et al."Multiresponsive UV-One-Photon Absorption, Near-Infrared-Two Photon Absorption, and X/gamma-Photoelectric Absorption Luminescence in One [Cu4I4] Compound".INORGANIC CHEMISTRY 58.16(2019):10736.
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