Rapid growth of large-area single-crystal graphene film by seamless stitching using resolidified copper foil on a molybdenum substrate

doi:10.1039/c9ta05483a

SIC OpenIR

	Rapid growth of large-area single-crystal graphene film by seamless stitching using resolidified copper foil on a molybdenum substrate
	Cheng, Yuan; Bi, Hui; Che, Xiangli; Zhao, Wei; Li, Dezeng; Huang, Fuqiang
	2019-08-21
Source Publication	JOURNAL OF MATERIALS CHEMISTRY A
ISSN	2050-7488
Volume	7 Issue:31 Pages:18373
Subtype	Article
Abstract	Graphene grain boundaries are inevitably formed during the stitching of graphene domains, consequently degrading the graphene film quality. Herein, we have developed a new strategy to grow large-area single-crystal graphene film using resolidified Cu foil on a Mo substrate. The Cu foil resolidifies into a quasi-atomically smooth Cu film, and recrystallizes into a single-crystal Cu (111) film sticking to the Mo foil surface after annealing above the Cu melting point under a H-2 atmosphere. A single-crystal graphene film of more than 2 inches in size is obtained by seamless stitching of more than 99% ultra-highly oriented single-crystal graphene domains of similar to 500 mu m on the resolidified Cu (111) surface, and it shows a low average sheet resistance of 315 omega sq(-1) and a high optical transmittance of similar to 97.6%. Moreover, the field-effect mobility of the single-crystal graphene film reaches up to 11 500 cm(2) V-1 s(-1), significantly higher than that of polycrystalline graphene film (similar to 4260 cm(2) V-1 s(-1)). This approach can easily be scaled up to achieve large-area and high-quality graphene film with a single crystal nature, and thereby realize various industrial-level applications at low cost.
DOI	10.1039/c9ta05483a
Language	英语
WOS Research Area	Chemistry ; Energy & Fuels ; Materials Science
Publisher	ROYAL SOC CHEMISTRY
Citation statistics	Cited Times:2[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.sic.ac.cn/handle/331005/26893
Collection	中国科学院上海硅酸盐研究所
Recommended Citation GB/T 7714	Cheng, Yuan,Bi, Hui,Che, Xiangli,et al. Rapid growth of large-area single-crystal graphene film by seamless stitching using resolidified copper foil on a molybdenum substrate[J]. JOURNAL OF MATERIALS CHEMISTRY A,2019,7(31):18373.
APA	Cheng, Yuan,Bi, Hui,Che, Xiangli,Zhao, Wei,Li, Dezeng,&Huang, Fuqiang.(2019).Rapid growth of large-area single-crystal graphene film by seamless stitching using resolidified copper foil on a molybdenum substrate.JOURNAL OF MATERIALS CHEMISTRY A,7(31),18373.
MLA	Cheng, Yuan,et al."Rapid growth of large-area single-crystal graphene film by seamless stitching using resolidified copper foil on a molybdenum substrate".JOURNAL OF MATERIALS CHEMISTRY A 7.31(2019):18373.

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