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An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation
Zhou, Beibei; Zeng, Tengwu; Shi, Zhao-Lin; Zhang, Gen; Horike, Satoshi; Zhang, Yue-Biao
2019-10-15
Source PublicationCHEMISTRY-AN ASIAN JOURNAL
ISSN1861-4728
Volume14Issue:20Pages:3552
SubtypeArticle
AbstractThe function of allosteric enzymes can be activated or inhibited through binding of specific effector molecules. Herein, we describe how the skeletal deformation, pore configuration, and ultimately adsorptive behavior of a dynamic metal-organic framework (MOF), (Me2NH2)[In(atp)](2) (in which atp=2-aminoterephthalate), are controlled by the allocation and orientation of its counter ions triggered by the inclusion/removal of different guest molecules. The power of such allosteric control in MOFs is highlighted through the optimization of the hydrocarbon separation performance by achieving multiple pore configurations but without altering the chemical composition.
Keywordadsorption gas separation metal-organic frameworks porous materials solvent effects
DOI10.1002/asia.201900239
Language英语
WOS Research AreaChemistry
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/26773
Collection中国科学院上海硅酸盐研究所
Recommended Citation
GB/T 7714
Zhou, Beibei,Zeng, Tengwu,Shi, Zhao-Lin,et al. An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation[J]. CHEMISTRY-AN ASIAN JOURNAL,2019,14(20):3552.
APA Zhou, Beibei,Zeng, Tengwu,Shi, Zhao-Lin,Zhang, Gen,Horike, Satoshi,&Zhang, Yue-Biao.(2019).An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation.CHEMISTRY-AN ASIAN JOURNAL,14(20),3552.
MLA Zhou, Beibei,et al."An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation".CHEMISTRY-AN ASIAN JOURNAL 14.20(2019):3552.
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