KMS Shanghai Institute of Ceramics，Chinese Academy of Sciences
| The dielectric, thermal properties and crystallization mechanism of Li-Al - B-Si - O glass - Ceramic systems as a new ULTCC material | |
| Chen, Guanyu; Ma, Mingsheng; Wei, Anqing; Liu, Zhifu; Zhang, Faqiang; Mitchell, Arnan; Li, Yongxiang | |
| 2019-11-01 | |
| Source Publication | CERAMICS INTERNATIONAL
 |
| ISSN | 0272-8842 |
| Volume | 45Issue:16Pages:19689 |
| Subtype | Article |
| Abstract | Li-Al-B-Si-O (LABS) glass-ceramics with a sintering temperature of 600 degrees C were studied for ultra-low temperature co-fired ceramics (ULTCC) applications. The crystal phase of LABS glass-ceramics is dendritic beta-spodumene. The permittivity and dielectric loss of LABS glass-ceramics are epsilon(r) = 5.8 and tg delta = 1.3 x 10(-3) at 10 MHz, respectively. The coefficient of thermal expansion (CTE) of LABS glass-ceramics is 3.23 ppm/degrees C, which is close to that of silicon. The dielectric and thermal properties of LABS glass-ceramics are closely correlated to the degree of its crystallization. The permittivity decreases continually while the dielectric loss decreases first and slightly increases with the increasing of crystallization of beta-spodumene. The CTE of LABS glass-ceramics decreases as beta-spodumene crystallized from LABS glass. The crystallization kinetic and mechanism of LABS glass-ceramics indicate that the beta-spodumene crystallizes in a two-dimensional interfacial growth mechanism due to the migration of Li-ions. The diffusion coefficients derived from energy-dispersive X-ray spectroscopy (EDS) results indicated that both Al and Ag electrodes have good compatibilities with ULTCC tapes, which could reduce the cost of multilayer electro-ceramic devices dramatically by using the ULTCC and base metallization. |
| Keyword | LABS glass-ceramic ULTCC Dielectric property CTE Crystallization kinetic Base metallization |
| DOI | 10.1016/j.ceramint.2019.06.220 |
| Language | 英语 |
| WOS Research Area | Materials Science |
| Publisher | ELSEVIER SCI LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sic.ac.cn/handle/331005/26738 |
| Collection | 中国科学院上海硅酸盐研究所 |
| Recommended Citation GB/T 7714 | Chen, Guanyu,Ma, Mingsheng,Wei, Anqing,et al. The dielectric, thermal properties and crystallization mechanism of Li-Al - B-Si - O glass - Ceramic systems as a new ULTCC material[J]. CERAMICS INTERNATIONAL,2019,45(16):19689. |
| APA | Chen, Guanyu.,Ma, Mingsheng.,Wei, Anqing.,Liu, Zhifu.,Zhang, Faqiang.,...&Li, Yongxiang.(2019).The dielectric, thermal properties and crystallization mechanism of Li-Al - B-Si - O glass - Ceramic systems as a new ULTCC material.CERAMICS INTERNATIONAL,45(16),19689. |
| MLA | Chen, Guanyu,et al."The dielectric, thermal properties and crystallization mechanism of Li-Al - B-Si - O glass - Ceramic systems as a new ULTCC material".CERAMICS INTERNATIONAL 45.16(2019):19689. |
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