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Influence of Tb3+concentration on the optical properties and Verdet constant of magneto-optic ABS-PZZ glass
Ding, Jingxin1,2; Man, Peiwen2; Chen, Qinming1; Guo, Li1; Hu, Xin1; Xiao, Yunyun1; Su, Liangbi2; Wu, Anhua2; Zhou, Yanyan1; Zeng, Fanming1
2017
Source PublicationOptical Materials
ISSN09253467
Volume69Pages:202-206
AbstractHighly transparent magneto-optical (MO) glasses (heavily xTb-doped SiO2-B2O3-P2O5-ZnO-ZrO, x = 15, 25, 32, 35, 40 mol%) were prepared by high temperature melting-quenching technique. The optical and magnetooptical properties have been measured at room temperature. The infrared transmission spectra and XRD confirms that [BO4], [BO3], [SiO4], [PO4], [BPO4] units the glass structure without crystallization by accommodating more Tb ions. The typical absorption bands could be observed in the UV–vis transmission spectra ascribing to 5d–4f electronic transition of Tb3+and the absorption edges shift to a longer wavelength by increasing the Terbium ions content. The intensity of the emission peaks and decay time which is in the order of milliseconds decreases caused by concentration quenching. The cross-relaxation is responsible for the luminescence gradually disappearing of5D3. The highest Verdet constant of the prepared glasses at room temperature @632.8 nm is −136.648 rad/T/m and the contribution V/N of each ion Tb is proportional to mole volume. © 2017 Elsevier B.V.
DOI10.1016/j.optmat.2017.04.036
EI Accession Number20171703608530
EI KeywordsOptical properties
EI Classification Number537.1 Heat Treatment Processes - 701.1 Electricity: Basic Concepts and Phenomena - 741.1 Light/Optics - 804.2 Inorganic Compounds - 812.3 Glass
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Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/25890
Collection中国科学院上海硅酸盐研究所
Corresponding AuthorWu, Anhua
Affiliation1.School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun; 130022, China;
2.Synthetic Single Crystal Research Center and Key Laboratory of Transparent and Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China
Recommended Citation
GB/T 7714
Ding, Jingxin,Man, Peiwen,Chen, Qinming,et al. Influence of Tb3+concentration on the optical properties and Verdet constant of magneto-optic ABS-PZZ glass[J]. Optical Materials,2017,69:202-206.
APA Ding, Jingxin.,Man, Peiwen.,Chen, Qinming.,Guo, Li.,Hu, Xin.,...&Zeng, Fanming.(2017).Influence of Tb3+concentration on the optical properties and Verdet constant of magneto-optic ABS-PZZ glass.Optical Materials,69,202-206.
MLA Ding, Jingxin,et al."Influence of Tb3+concentration on the optical properties and Verdet constant of magneto-optic ABS-PZZ glass".Optical Materials 69(2017):202-206.
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