Influence of Tb3+concentration on the optical properties and Verdet constant of magneto-optic ABS-PZZ glass

doi:10.1016/j.optmat.2017.04.036

SIC OpenIR

	Influence of Tb3+concentration on the optical properties and Verdet constant of magneto-optic ABS-PZZ glass
	Ding, Jingxin 1,2; Man, Peiwen 2; Chen, Qinming 1; Guo, Li 1; Hu, Xin 1; Xiao, Yunyun 1; Su, Liangbi 2; Wu, Anhua 2; Zhou, Yanyan 1; Zeng, Fanming 1
	2017
发表期刊	Optical Materials
ISSN	09253467
卷号	69 页码:202-206
摘要	Highly transparent magneto-optical (MO) glasses (heavily xTb-doped SiO2-B2O3-P2O5-ZnO-ZrO, x = 15, 25, 32, 35, 40 mol%) were prepared by high temperature melting-quenching technique. The optical and magnetooptical properties have been measured at room temperature. The infrared transmission spectra and XRD confirms that [BO4], [BO3], [SiO4], [PO4], [BPO4] units the glass structure without crystallization by accommodating more Tb ions. The typical absorption bands could be observed in the UV–vis transmission spectra ascribing to 5d–4f electronic transition of Tb3+and the absorption edges shift to a longer wavelength by increasing the Terbium ions content. The intensity of the emission peaks and decay time which is in the order of milliseconds decreases caused by concentration quenching. The cross-relaxation is responsible for the luminescence gradually disappearing of5D3. The highest Verdet constant of the prepared glasses at room temperature @632.8 nm is −136.648 rad/T/m and the contribution V/N of each ion Tb is proportional to mole volume. © 2017 Elsevier B.V.
DOI	10.1016/j.optmat.2017.04.036
EI入藏号	20171703608530
EI主题词	Optical properties
EI分类号	537.1 Heat Treatment Processes - 701.1 Electricity: Basic Concepts and Phenomena - 741.1 Light/Optics - 804.2 Inorganic Compounds - 812.3 Glass
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.sic.ac.cn/handle/331005/25890
专题	中国科学院上海硅酸盐研究所
通讯作者	Wu, Anhua
作者单位	1.School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun; 130022, China; 2.Synthetic Single Crystal Research Center and Key Laboratory of Transparent and Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China
推荐引用方式 GB/T 7714	Ding, Jingxin,Man, Peiwen,Chen, Qinming,et al. Influence of Tb3+concentration on the optical properties and Verdet constant of magneto-optic ABS-PZZ glass[J]. Optical Materials,2017,69:202-206.
APA	Ding, Jingxin.,Man, Peiwen.,Chen, Qinming.,Guo, Li.,Hu, Xin.,...&Zeng, Fanming.(2017).Influence of Tb3+concentration on the optical properties and Verdet constant of magneto-optic ABS-PZZ glass.Optical Materials,69,202-206.
MLA	Ding, Jingxin,et al."Influence of Tb3+concentration on the optical properties and Verdet constant of magneto-optic ABS-PZZ glass".Optical Materials 69(2017):202-206.