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Two-dimensional MXene Ti3C2produced by exfoliation of Ti3AlC2
Feng, Aihu1,2; Yu, Yun1; Wang, Yong1,2; Jiang, Feng1,2; Yu, Yang1; Mi, Le1; Song, Lixin1
2017
发表期刊Materials and Design
ISSN02641275
卷号114页码:161-166
摘要MXene, a new family of 2D materials, possesses excellent electrical conductivity and hydrophilicity. To date, the majority of MXenes are only successfully produced by exfoliating the MAX phases with high concentration hydrofluoric acid (HF). In this study, the 2D MXene Ti3C2with larger interplanar spacing was successfully obtained by etching Ti3AlC2with bifluoride (NaHF2, KHF2, NH4HF2) in single-stage process. The morphology, structure and element composition of prepared Ti3C2samples were characterized by scanning electron smicroscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive spectrometer (EDS). The synthesis mechanism of Ti3C2was elaborately demonstrated. The possible reaction equations between Ti3AlC2and different bifluorides were generalized, indicating the formation of hydrosoluble by-products of Na3AlF6,K3AlF6and (NH4)3AlF6. This work presents a safely effective method to synthesize the 2D nanocrystals MXene. © 2016 Elsevier Ltd
DOI10.1016/j.matdes.2016.10.053
EI入藏号20165103145946
EI主题词Titanium compounds
EI分类号741.3 Optical Devices and Systems - 804.2 Inorganic Compounds
引用统计
文献类型期刊论文
条目标识符http://ir.sic.ac.cn/handle/331005/25856
专题中国科学院上海硅酸盐研究所
作者单位1.Key Laboratory of Inorganic Coating Materials CAS, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China;
2.University of Chinese Academy of Sciences, Beijing; 100049, China
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Feng, Aihu,Yu, Yun,Wang, Yong,et al. Two-dimensional MXene Ti3C2produced by exfoliation of Ti3AlC2[J]. Materials and Design,2017,114:161-166.
APA Feng, Aihu.,Yu, Yun.,Wang, Yong.,Jiang, Feng.,Yu, Yang.,...&Song, Lixin.(2017).Two-dimensional MXene Ti3C2produced by exfoliation of Ti3AlC2.Materials and Design,114,161-166.
MLA Feng, Aihu,et al."Two-dimensional MXene Ti3C2produced by exfoliation of Ti3AlC2".Materials and Design 114(2017):161-166.
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