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The structure of filled skutterudites and the local vibration behavior of the filling atom
Zhou, Xiaojuan1,2,3; Zong, Peng-an4,5; Chen, Xihong5; Tao, Juzhou1,2; Lin, He6
2017
Source PublicationPhysica B: Condensed Matter
ISSN09214526
Volume507Pages:131-133
AbstractBoth of atomic pair distribution function (PDF) and extended x-ray absorption fine structure (EXAFS) experiments have been carried out on unfilled and Yb-filled skutterudites YbxCo4Sb12(x=0, 0.15, 0.2 and 0.25) samples. The structure refinements on PDF data confirm the large amplitude vibration of Yb atom and the dependence of Yb vibration amplitude on the filling content. Temperature dependent EXAFS experiment on filled skutterudites have been carried out at Yb L-edge in order to explore the local vibration behavior of filled atom. EXAFS experiments show that the Einstein temperature of the filled atom is very low (70.9 K) which agrees with the rattling behavior. © 2016 Elsevier B.V.
DOI10.1016/j.physb.2016.12.007
EI Accession Number20165003107747
EI KeywordsDistribution functions
EI Classification Number482.2 Minerals - 547.2 Rare Earth Metals - 711 Electromagnetic Waves - 711.2 Electromagnetic Waves in Relation to Various Structures - 922.1 Probability Theory - 931.3 Atomic and Molecular Physics
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Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/25838
Collection中国科学院上海硅酸盐研究所
Affiliation1.Institute of High Energy Physics, Chinese Academy of Sciences, Beijing; 100049, China;
2.Dongguan Institute of Neutron Science, Dongguan; 523808, China;
3.University of Chinese Academy of Sciences, Beijing; 100049, China;
4.State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing; 100084, China;
5.Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China;
6.Shanghai Institute of Applied Physics, Chinese Academy of Science, Shanghai; 201204, China
Recommended Citation
GB/T 7714
Zhou, Xiaojuan,Zong, Peng-an,Chen, Xihong,et al. The structure of filled skutterudites and the local vibration behavior of the filling atom[J]. Physica B: Condensed Matter,2017,507:131-133.
APA Zhou, Xiaojuan,Zong, Peng-an,Chen, Xihong,Tao, Juzhou,&Lin, He.(2017).The structure of filled skutterudites and the local vibration behavior of the filling atom.Physica B: Condensed Matter,507,131-133.
MLA Zhou, Xiaojuan,et al."The structure of filled skutterudites and the local vibration behavior of the filling atom".Physica B: Condensed Matter 507(2017):131-133.
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