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CaxSr0.3−xBa0.7Nb2O6lead-free pyroelectric ceramics with high depoling temperature
Chen, Hui1,2; Guo, Shaobo1; Dong, Xianlin1; Cao, Fei1; Mao, Chaoliang1; Wang, Genshui1
2017
发表期刊Journal of Alloys and Compounds
ISSN09258388
卷号695页码:2723-2729
摘要CaxSr0.3−xBa0.7Nb2O6[CSBN (x), x = 0.00, 0.10, 0.20, and 0.30] lead-free ceramics were fabricated by traditional solid-state reaction technique. The morphology, structure, dielectric, ferroelectric and pyroelectric properties of CSBN (x) ceramics were systematically studied. The thermal depoling behaviors were evaluated through measurements of temperature dependence of piezoelectric constant (d33). All CSBN (x) ceramics exhibited obvious diffuse phase transitions and maximum dielectric constant (Εm) increased monotonically with x. The ferroelectric and pyroelectric properties of CSBN (x) have been enhanced remarkably due to Ca addition. The remnant polarization (Pr) and pyroelectric coefficient (p) of CSBN (0.30) samples reached 4.95 μC/cm2and 1.30 × 10−8C/cm2K which roughly tripled and doubled pure SBN. What's more, CSBN (0.20) samples achieved rather high pyroelectric figure of merit of voltage (Fv= 0.0203 m2/C) which is superior to many other lead-free materials and pyroelectric figure of merit of detectivity (FD) for CSBN (0.20) and CSBN (0.30) samples both soared to 0.61 × 10−5Pa−1/2. The most inspiring part is the depoling temperature and Curie temperature noticeably shifted to higher temperature region owing to Ca addition. These results unveil the potential of CSBN (x) ceramics for infrared detector applications. © 2016 Elsevier B.V.
DOI10.1016/j.jallcom.2016.11.192
EI入藏号20165203189307
EI主题词Calcium
EI分类号549.2 Alkaline Earth Metals - 641.1 Thermodynamics - 701.1 Electricity: Basic Concepts and Phenomena - 708.1 Dielectric Materials - 802.2 Chemical Reactions - 812.1 Ceramics
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sic.ac.cn/handle/331005/25730
专题中国科学院上海硅酸盐研究所
作者单位1.Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai; 200050, China;
2.University of the Chinese Academy of Sciences, Beijing; 100049, China
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GB/T 7714
Chen, Hui,Guo, Shaobo,Dong, Xianlin,et al. CaxSr0.3−xBa0.7Nb2O6lead-free pyroelectric ceramics with high depoling temperature[J]. Journal of Alloys and Compounds,2017,695:2723-2729.
APA Chen, Hui,Guo, Shaobo,Dong, Xianlin,Cao, Fei,Mao, Chaoliang,&Wang, Genshui.(2017).CaxSr0.3−xBa0.7Nb2O6lead-free pyroelectric ceramics with high depoling temperature.Journal of Alloys and Compounds,695,2723-2729.
MLA Chen, Hui,et al."CaxSr0.3−xBa0.7Nb2O6lead-free pyroelectric ceramics with high depoling temperature".Journal of Alloys and Compounds 695(2017):2723-2729.
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