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Nickle Electrodes for High-temperature Proton-conducting Electrolytes: Preparation by Electroless Plating and Electrochemical Performance
Wen, Ya-Bing1,2; Zhang, Jing-Chao2; Ye, Xiao-Feng2; Wang, Yong1; Han, Jin-Duo2; Luo, Wen-Hua3; Gu, Sui2; Meng, Jian-Bo3; Wen, Zhao-Yin2
2017
Source PublicationWuji Cailiao Xuebao/Journal of Inorganic Materials
ISSN1000324X
Volume32Issue:12Pages:1250-1256
AbstractNickel layers were deposited on the surface of high-temperature proton-conducting CaZr0.9In0.1O3-δ(CZI) electrolytes by an electroless plating technique. Effects of acid etching and reduction processes on electrode surface morphology and electrolyte adherence to electrodes were investigated by SEM observation. The results showed that the electrodes prepared by a two-step electroless plating process in HNO3-HCl etching solution with hydrazine reducing agent were uniform and well connected to the electrolyte surface. Conductivity and proton transport rate between Ni-CZI symmetric cell and Pt-CZI symmetric cell were compared by electrochemical impedance spectroscopy and concentration cell test. The total conductivity of the Ni-CZI symmetric cell was 4.131×10-4S/cm at 800, and the proton transport rates of the Ni-CZI symmetric cell were all almost 100% at the operating temperature higher than 400. The nickel electrode prepared by two-step electroless plating was achievable at low cost and had a comparable catalytic performance to that of platinum electrode, indicating it a promising candidate to replace the noble platinum catalyst electrode. © 2017, Science Press. All right reserved.
DOI10.15541/jim20170112
EI Accession Number20182005193731
EI KeywordsElectrochemical electrodes
EI Classification Number539.3.2 Electroless Plating - 547.1 Precious Metals - 548.1 Nickel - 702 Electric Batteries and Fuel Cells - 801 Chemistry - 802.2 Chemical Reactions - 803 Chemical Agents and Basic Industrial Chemicals - 804 Chemical Products Generally
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Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/25630
Collection中国科学院上海硅酸盐研究所
Affiliation1.School of Environmental and Chemical Engineering, Shanghai University, Shanghai; 200444, China;
2.CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China;
3.China Academy of Engineering Physics, Mianyang; Sichuan; 621900, China
Recommended Citation
GB/T 7714
Wen, Ya-Bing,Zhang, Jing-Chao,Ye, Xiao-Feng,et al. Nickle Electrodes for High-temperature Proton-conducting Electrolytes: Preparation by Electroless Plating and Electrochemical Performance[J]. Wuji Cailiao Xuebao/Journal of Inorganic Materials,2017,32(12):1250-1256.
APA Wen, Ya-Bing.,Zhang, Jing-Chao.,Ye, Xiao-Feng.,Wang, Yong.,Han, Jin-Duo.,...&Wen, Zhao-Yin.(2017).Nickle Electrodes for High-temperature Proton-conducting Electrolytes: Preparation by Electroless Plating and Electrochemical Performance.Wuji Cailiao Xuebao/Journal of Inorganic Materials,32(12),1250-1256.
MLA Wen, Ya-Bing,et al."Nickle Electrodes for High-temperature Proton-conducting Electrolytes: Preparation by Electroless Plating and Electrochemical Performance".Wuji Cailiao Xuebao/Journal of Inorganic Materials 32.12(2017):1250-1256.
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