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Large-Scale Multifunctional Electrochromic-Energy Storage Device Based on Tungsten Trioxide Monohydrate Nanosheets and Prussian White
Bi, Zhijie1,2; Li, Xiaomin1; Chen, Yongbo1,2; He, Xiaoli1,2; Xu, Xiaoke1,3; Gao, Xiangdong1
2017
Source PublicationACS Applied Materials and Interfaces
ISSN19448244
Volume9Issue:35Pages:29872-29880
AbstractA high-performance electrochromic-energy storage device (EESD) is developed, which successfully realizes the multifunctional combination of electrochromism and energy storage by constructing tungsten trioxide monohydrate (WO3·H2O) nanosheets and Prussian white (PW) film as asymmetric electrodes. The EESD presents excellent electrochromic properties of broad optical modulation (61.7%), ultrafast response speed (1.84/1.95 s), and great coloration efficiency (139.4 cm2C-1). In particular, remarkable cyclic stability (sustaining 82.5% of its initial optical modulation after 2500 cycles as an electrochromic device, almost fully maintaining its capacitance after 1000 cycles as an energy storage device) is achieved. The EESD is also able to visually detect the energy storage level via reversible and fast color changes. Moreover, the EESD can be combined with commercial solar cells to constitute an intelligent operating system in the architectures, which would realize the adjustment of indoor sunlight and the improvement of physical comfort totally by the rational utilization of solar energy without additional electricity. Besides, a scaled-up EESD (10 × 11 cm2) is further fabricated as a prototype. Such promising EESD shows huge potential in practically serving as electrochromic smart windows and energy storage devices. © 2017 American Chemical Society.
DOI10.1021/acsami.7b08656
EI Accession Number20173704146731
EI KeywordsElectric energy storage
EI Classification Number525.7 Energy Storage - 657.1 Solar Energy and Phenomena - 702.3 Solar Cells - 714 Electronic Components and Tubes - 741.1 Light/Optics - 761 Nanotechnology - 933 Solid State Physics
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Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/25625
Collection中国科学院上海硅酸盐研究所
Affiliation1.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, No. 1295 Dingxi Road, Shanghai; 200050, China;
2.University of Chinese Academy of Sciences, No. 19A Yuquan Road, Beijing; 100049, China;
3.School of Materials Science and Engineering, Shanghai Institute of Technology, No. 100 Haiquan Road, Shanghai; 201418, China
Recommended Citation
GB/T 7714
Bi, Zhijie,Li, Xiaomin,Chen, Yongbo,et al. Large-Scale Multifunctional Electrochromic-Energy Storage Device Based on Tungsten Trioxide Monohydrate Nanosheets and Prussian White[J]. ACS Applied Materials and Interfaces,2017,9(35):29872-29880.
APA Bi, Zhijie,Li, Xiaomin,Chen, Yongbo,He, Xiaoli,Xu, Xiaoke,&Gao, Xiangdong.(2017).Large-Scale Multifunctional Electrochromic-Energy Storage Device Based on Tungsten Trioxide Monohydrate Nanosheets and Prussian White.ACS Applied Materials and Interfaces,9(35),29872-29880.
MLA Bi, Zhijie,et al."Large-Scale Multifunctional Electrochromic-Energy Storage Device Based on Tungsten Trioxide Monohydrate Nanosheets and Prussian White".ACS Applied Materials and Interfaces 9.35(2017):29872-29880.
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