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Variable texture few-layer ordered macroporous carbon for high-performance electrochemical capacitors
Xu, Feng1,2; Sun, Peng1,2; Qian, Meng1,2; Lin, Tianquan1; Huang, Fuqiang1,3
2017
发表期刊Journal of Materials Chemistry A
ISSN20507488
卷号5期号:48页码:25171-25176
摘要Few-layer carbon with an interconnected ordered macroporous structure has unique attributes which are appealing for many applications in energy storage, catalyst support, and thermal management. But to date the preparation of such structures is still challenging. Here we report an ordered macroporous few-layer carbon with variable texture prepared by chemical vapour deposition, using porous opal infiltrated with alumina sol as the template. By adjusting the composition of the interfacial phase, the ordered macroporous structure varies from a square network to a honeycomb structure; this process may be an important new method to control micro-morphology. Aided by its high specific surface area (1240 m2g-1) and meso/microporous structure, this material takes full advantage of the electrochemical attributes of few-layer carbon, featuring a specific capacitance of 415 F g-1, of which 94.5% is retained after 10000 charging/discharging cycles. Such capabilities may accelerate the adoption of porous carbon for energy storage applications. © 2017 The Royal Society of Chemistry.
DOI10.1039/c7ta09633j
EI入藏号20175104560561
EI主题词Carbon
EI分类号408.2 Structural Members and Shapes - 525.7 Energy Storage - 802.2 Chemical Reactions - 804 Chemical Products Generally - 804.2 Inorganic Compounds - 951 Materials Science
引用统计
文献类型期刊论文
条目标识符http://ir.sic.ac.cn/handle/331005/25617
专题中国科学院上海硅酸盐研究所
作者单位1.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China;
2.University of Chinese Academy of Sciences, 19 Yuquan Road, Beijing; 100049, China;
3.State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing; 100871, China
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GB/T 7714
Xu, Feng,Sun, Peng,Qian, Meng,et al. Variable texture few-layer ordered macroporous carbon for high-performance electrochemical capacitors[J]. Journal of Materials Chemistry A,2017,5(48):25171-25176.
APA Xu, Feng,Sun, Peng,Qian, Meng,Lin, Tianquan,&Huang, Fuqiang.(2017).Variable texture few-layer ordered macroporous carbon for high-performance electrochemical capacitors.Journal of Materials Chemistry A,5(48),25171-25176.
MLA Xu, Feng,et al."Variable texture few-layer ordered macroporous carbon for high-performance electrochemical capacitors".Journal of Materials Chemistry A 5.48(2017):25171-25176.
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