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Enhanced Nitrogen Photofixation over LaFeO3via Acid Treatment
Sun, Xiang1,2; Jiang, Dong1; Zhang, Ling1; Sun, Songmei1; Wang, Wenzhong1
2017
Source PublicationACS Sustainable Chemistry and Engineering
Volume5Issue:11Pages:9965-9971
AbstractThe N2photofixation presents a green and eco-friendly ammonia synthesis approach. However, present strategies for light-induced N2activation suffer from low efficiency and instability, largely hindering the development of this technology. Herein, we report the LaFeO3co-optimization of N2activation as well as subsequent photoinduced protonation with the further phosphate acid treatment. Efficient ammonia evolution rate reached 250 μmol g-1h-1over LaFeO3under simulated sunlight with appropriate acid treatment. The enhancement of phosphate modified samples was mainly attributed to the "pull and push" effect. The hydrogen bonding centers and transition metals (Fe) served as two separation active sites, which improves the adsorption and activation of dinitrogen. In addition, the facilitation of H2O dissociation was also achieved after phosphate modification. These results suggested an alternative N2photofixation strategy of traditional organic and precious metallic additives for efficient ammonia synthesis. © 2017 American Chemical Society.
DOI10.1021/acssuschemeng.7b01912
EI Accession Number20174604394989
EI KeywordsIron compounds
EI Classification Number531 Metallurgy and Metallography - 741.1 Light/Optics - 801.4 Physical Chemistry - 804 Chemical Products Generally - 804.2 Inorganic Compounds
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Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/25461
Collection中国科学院上海硅酸盐研究所
Affiliation1.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai; 200050, China;
2.University of Chinese Academy of Sciences, Beijing; 100049, China
Recommended Citation
GB/T 7714
Sun, Xiang,Jiang, Dong,Zhang, Ling,et al. Enhanced Nitrogen Photofixation over LaFeO3via Acid Treatment[J]. ACS Sustainable Chemistry and Engineering,2017,5(11):9965-9971.
APA Sun, Xiang,Jiang, Dong,Zhang, Ling,Sun, Songmei,&Wang, Wenzhong.(2017).Enhanced Nitrogen Photofixation over LaFeO3via Acid Treatment.ACS Sustainable Chemistry and Engineering,5(11),9965-9971.
MLA Sun, Xiang,et al."Enhanced Nitrogen Photofixation over LaFeO3via Acid Treatment".ACS Sustainable Chemistry and Engineering 5.11(2017):9965-9971.
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