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Study of arsenic in Famille rose porcelain from the Imperial Palace of Qing Dynasty, Beijing, China
Li, Yuanqiu1,2; Zhu, Jian1,2; Ji, Luoyuan3; Shan, Yingying3; Jiang, Sheng4; Chen, Guang5,6; Sciau, Philippe7; Wang, Wenxuan1,2; Wang, Changsui1,2
2018
Source PublicationCeramics International
ISSN02728842
Volume44Issue:2Pages:1627-1632
AbstractFamille rose porcelain from the imperial workshop was one of the symbols of the highest level of manufacturing techniques in ancient China. It was very precious and only owned by the royals at the early stage. The major feature of famille rose is the use of opaque white pigment. Considered to originate in Europe, this technique was a witness of technological exchanges between China and European countries in the 17th–18th centuries. However, limited by its preciousness, most of the previous studies focused on the chemical composition of famille rose relics via nondestructive analysis methods. In this work, selected samples excavated at the Forbidden City of China were analysed by microscopy observation, Laser Ablation Inductive Coupled Plasma-Atomic Emission Spectrometry (LA-ICP-AES), synchrotron radiation X-ray Absorption Near-Edge Spectroscopy (XANES) and micro X-ray Diffraction (μXRD). The results revealed that two painting methods which related to Chinese and European techniques were applied. Chemical composition indicate that opaque white is a kind of arsenic-lead white. Moreover, the synchrotron radiation results show that As5+is the major state in opaque white and exists mostly probably as AsO43--ion. © 2017 Elsevier Ltd and Techna Group S.r.l.
DOI10.1016/j.ceramint.2017.10.084
PublisherElsevier Ltd
EI KeywordsPorcelain
EI Classification Number641.2 Heat Transfer - 711 Electromagnetic Waves - 804 Chemical Products Generally - 812.1 Ceramics - 932.1.1 Particle Accelerators
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Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sic.ac.cn/handle/331005/25186
Collection中国科学院上海硅酸盐研究所
Affiliation1.Key Laboratory of Vertebrate Evolution and Human Origins of Chinese Academy of Sciences, Institute of Vertebrate Paleontology and Paleoanthropology, Chinese Academy of Sciences, Beijing; 100044, China;
2.Department of Archaeology and Anthropology, University of Chinese Academy of Sciences, Beijing; 100049, China;
3.The Palace Museum Archaeological Institute, Beijing; 100009, China;
4.Shanghai Synchrotron Radiation Facilities, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai; 201204, China;
5.Institute of Health Sciences, Anhui University, Hefei; 230601, China;
6.Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing; 100049, China;
7.CEMES, CNRS, Toulouse University, Toulouse; 31055, France
Recommended Citation
GB/T 7714
Li, Yuanqiu,Zhu, Jian,Ji, Luoyuan,et al. Study of arsenic in Famille rose porcelain from the Imperial Palace of Qing Dynasty, Beijing, China[J]. Ceramics International,2018,44(2):1627-1632.
APA Li, Yuanqiu.,Zhu, Jian.,Ji, Luoyuan.,Shan, Yingying.,Jiang, Sheng.,...&Wang, Changsui.(2018).Study of arsenic in Famille rose porcelain from the Imperial Palace of Qing Dynasty, Beijing, China.Ceramics International,44(2),1627-1632.
MLA Li, Yuanqiu,et al."Study of arsenic in Famille rose porcelain from the Imperial Palace of Qing Dynasty, Beijing, China".Ceramics International 44.2(2018):1627-1632.
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